4,4′-Azopyridine
ALDRICH/705055
Synonym: Azobis(4-pyridine)
CAS Number: 2632-99-7
Empirical Formula (Hill Notation): C10H8N4
Molecular Weight: 184.20
MDL Number: MFCD00129061
Linear Formula: C10H8N4
Product Type: Chemical
form | solid |
InChI | 1S/C10H8N4/c1-5-11-6-2-9( |
InChI key | XUPMSLUFFIXCDA-UHFFFAOYSA |
mp | 96-101 °C |
SMILES string | c1cc(ccn1)N=Nc2ccncc2 |
Application: | 4,4′-Azopyridine can be used: • To prepare porous coordination polymers (PC • As a reagent for the conversion of aliphatic alcohols into disulfides under Mitsunobu conditions. • To prepare 4,4′-azopyridine-bridged binuclear zinc(II) complexes. |
Application: | Reactant for preparation of: • Flexible porous coordination polymers constructed from 1,2-bis(4-pyridyl)hydrazi • Metal-organic frameworks based on transition-metal carboxylate clusters as secondary building units • Heteroaromatic azo compounds under Mitsunobu conditions • MnII, CoII, and ZnII coordination polymers • Low-dimensional and porous coordination compounds capable of supramolecular aromatic interactions Reagent in: • Facile Mitsunobu esterification reactions |
General description: | 4,4′-Azopyridine is an aromatic heterocyclic compound used as a ligand in the formation of [HgI2(4,4′-azopyridine)]n complex. |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS06 |
Signal word | Danger |
Hazard statements | H301 - H315 - H319 - H335 |
Precautionary statements | P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xn |
Risk Statements | 22-36/37/38 |
Safety Statements | 26-36/37 |
RIDADR | UN 2811 6.1 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | 96-101 °C |
UNSPSC | 12352005 |