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4,4′-Azopyridine

ALDRICH/705055

Synonym: Azobis(4-pyridine)

CAS Number: 2632-99-7
Empirical Formula (Hill Notation): C10H8N4
Molecular Weight: 184.20
MDL Number: MFCD00129061
Linear Formula: C10H8N4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-705055-1G 1 g
 $199.00
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45-705055-5G 5 g
 $485.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 705055-5G

 

form solid
InChI 1S/C10H8N4/c1-5-11-6-2-9(1)13-14-10-3-7-12-8-4-10/h1-8H
InChI key XUPMSLUFFIXCDA-UHFFFAOYSA-N
mp 96-101 °C
Quality Level 100 
SMILES string c1cc(ccn1)N=Nc2ccncc2
Application: 4,4′-Azopyridine can be used:
• To prepare porous coordination polymers (PCPs) by reacting with Zn(NO3)2 and 1,4-benzenedicarboxylic acid.
• As a reagent for the conversion of aliphatic alcohols into disulfides under Mitsunobu conditions.
• To prepare 4,4′-azopyridine-bridged binuclear zinc(II) complexes.
Application: Reactant for preparation of:
• Flexible porous coordination polymers constructed from 1,2-bis(4-pyridyl)hydrazine via solvothermal in situ reduction reaction
• Metal-organic frameworks based on transition-metal carboxylate clusters as secondary building units
• Heteroaromatic azo compounds under Mitsunobu conditions
• MnII, CoII, and ZnII coordination polymers
• Low-dimensional and porous coordination compounds capable of supramolecular aromatic interactions

Reagent in:
• Facile Mitsunobu esterification reactions
General description: 4,4′-Azopyridine is an aromatic heterocyclic compound used as a ligand in the formation of [HgI2(4,4′-azopyridine)]n complex.
Packaging: 1, 5 g in glass bottle
mp 96-101 °C
UNSPSC 12352005

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