tert-Butyldichlorophosphine solution

ALDRICH/707230 - 1.0 M in diethyl ether

Synonym: (1,1-Dimethylethyl)phosphonous dichloride solution

CAS Number: 25979-07-1
Empirical Formula (Hill Notation): C₄H₉Cl₂P
Molecular Weight: 158.99
MDL Number: MFCD00013615
Linear Formula: C₄H₉Cl₂P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-707230-100ML	100 mL	$186.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in diethyl ether
density	0.766 g/mL at 25 °C
form	liquid
functional group	phosphine
InChI	1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3
InChI key	NMJASRUOIRRDSX-UHFFFAOYSA-N
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: ligand
SMILES string	CC(C)(C)P(Cl)Cl

Application:	Reactant for: • The preparation of Buchwald-type secondary phosphine oxide ligands • Asymmetric hydrogenation Reactant for the synthesis of: • Alkali metal complexes • P-Stereogenic compounds via kinetic deprotonation • Ortho-trifluoromethylphenyl-substituted phosphines
Packaging:	100 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H224 - H302 - H314 - H336
Precautionary statements	P210 - P233 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P403 + P233
Hazard Codes	F,C
Risk Statements	11-14-19-22-34-67
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGI
WGK Germany	WGK 3
Supplemental Hazard Statements	EUH014 - EUH019

Density	0.766 g/mL at 25 °C
UNSPSC	12352001

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