Silicomolybdic acid solution
ALDRICH/708348
Synonym: Keggin heteropoly acid
CAS Number: 11089-20-6
MDL Number: MFCD00054151
Linear Formula: H4SiO4 · 12MoO3
Product Type: Chemical
density | 1.156 g/mL at 25 °C |
form | liquid |
InChI | 1S/12Mo.O4Si.4H2O.32O/c;; |
InChI key | LMAWUDMBHTZUCF-UHFFFAOYSA |
refractive index | n |
SMILES string | O[Mo](=O)(=O)O[Mo](=O)(=O |
Application: | Reactant for: • Use in electrostatic synthesis of compounds comprising ultrathin layers of silicododecamolybdate anions and poly(allyl ammonium) cations • Preparation of charge transfer compounds with Keggin anions and 2,2′-biquinolinium |
Application: | Silicomolybdic acid (Keggin Acid, SMA) can be used to prepare supported acid catalysts for various organic transformations. For example, it is used to prepare: • SMA immobilized on mesoporous silica spheres for hydrolysis of ammonia borane. • SMA doped carbon-ceramic composite electrodes for electrocatalytic reduction of bromate. • SMA supported on silica gel (SiO2) for Hosomi–Sakurai allylation of carbonyl compounds. • SMA supported on mesoporous SiO2 hollow spheres for Friedel–Crafts alkylation reaction. |
Packaging: | 25, 125 g in poly bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-37-60 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Density | 1.156 g/mL at 25 °C |
Refractive Index | n |
UNSPSC | 12352301 |