RuCl[(R,R)-TsDPEN](mesitylene)

ALDRICH/708682 - 90%

Synonym: [N-[(1R,2R)-2-(Amino-κN)-1,2- diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro [(1,2,3,4,5,6-η)-1,3,5-trimethylbenzene]-ruthenium

CAS Number: 174813-82-2
Empirical Formula (Hill Notation): C₃₀H₃₃ClN₂O₂RuS
Molecular Weight: 622.18
MDL Number: MFCD12545951
Linear Formula: C₃₀H₃₃ClN₂O₂RuS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-708682-500MG	500 mg	$136.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	90%
form	solid
functional group	amine
	phenyl
InChI	1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1
InChI key	XBNBOGZUDCYNOJ-AGEKDOICSA-M
mp	241-249 °C
Quality Level	100
SMILES string	Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4
storage temp.	2-8°C

Application:	Takasago Ligands and Complexes for Asymmetric Reactions
Application:	RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize: • (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH). • Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
Legal Information:	Sold in collaboration with Takasago for research purposes only. WO9720789
Packaging:	100 mg in glass bottle
Packaging:	500 mg in amber glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	90%
mp	241-249 °C
Storage Temp.	2-8°C
UNSPSC	12352116

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