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(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

ALDRICH/708844

Synonym: (S,S)-AMAC

CAS Number: 259259-80-8
Empirical Formula (Hill Notation): C32H38CoN2O4
Molecular Weight: 573.59
MDL Number: MFCD06797062
Linear Formula: C32H38CoN2O4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-708844-100MG 100 mg
 $87.90
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form solid
InChI 1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15+,34-16+;/t31-,32-;/m0./s1
InChI key PHCQQLMRNZRDJA-OZXAGROVSA-L
mp 242-246 °C
optical activity [α]/D −309°, c = 0.1 in chloroform
SMILES string CC(=O)C1=C(C)O[Co]OC(C)=C(C=N[C@H]([C@@H](N=C1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O
Application: Catalyst for:
• Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
• Enantioselective borohydride reduction
• Preparation of ß-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
• Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones
Packaging: 100, 500 mg in amber glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp 242-246 °C
UNSPSC 12352000

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