1-Butyl-3-methylimidazolium hexafluorophosphate

ALDRICH/70956 - ≥97.0% (HPLC)

Synonym: BMIMPF₆

CAS Number: 174501-64-5
Empirical Formula (Hill Notation): C₈H₁₅F₆N₂P
Molecular Weight: 284.18
MDL Number: MFCD03093295
Linear Formula: C₈H₁₅F₆N₂P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-70956-5G	5 g	$85.10 1/EA		Add To Favorites
45-70956-50G	50 g	$338.00 1/EA		Add To Favorites
45-70956-250G	250 g	$1120.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥97.0% (HPLC)
density	1.38 g/mL at 20 °C (lit.)
form	liquid
InChI	1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
InChI key	IXQYBUDWDLYNMA-UHFFFAOYSA-N
Quality Level	200
refractive index	n20/D 1.411 (lit.)
SMILES string	F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1

Application:	1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions. It can also be used as a medium for reactions such as: • Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex. • Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant. • Lipase-catalyzed enantioselective acylation of allylic alcohols. • Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.
General description:	BMIMPF₆ is used as an efficient reaction medium for various synthetic and catalytic transformations. 1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF₆.
Packaging:	5, 50, 250 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥97.0% (HPLC)
Density	1.38 g/mL at 20 °C (lit.)
Refractive Index	n20/D 1.411 (lit.)
UNSPSC	12352100

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