Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine

ALDRICH/710385 - 95%

CAS Number: 136802-85-2
Empirical Formula (Hill Notation): C₁₈H₂₂ClO₂P
Molecular Weight: 336.79
MDL Number: MFCD01630810
Linear Formula: C₁₈H₂₂ClO₂P
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-710385-1G	1 g	$157.00 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

assay	95%
density	1.141 g/cm³ at 25 °C
form	liquid
functional group	phosphine
InChI	1S/C18H22ClO2P/c1-11-7-15(8-12(2)17(11)20-5)22(19)16-9-13(3)18(21-6)14(4)10-16/h7-10H,1-6H3
InChI key	JWCZKGYRAINWJA-UHFFFAOYSA-N
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: ligand
refractive index	n20/D 1.597
SMILES string	COc1c(C)cc(cc1C)P(Cl)c2cc(C)c(OC)c(C)c2

Application:	Reactant for: • Asymmetric organocatalytic electrophilic phosphination • Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands • Synthesis of ferrocene-based chiral diphosphines • Alcoholysis of phosphane-boranes • Asymmetric hydrogenations of bifep-type biferrocenes
Packaging:	1 g in glass bottle

Symbol	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280 - P305 + P351 + P338 - P310
Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-43-45
RIDADR	UN 1760 8 / PGIII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	95%
Density	1.141 g/cm³ at 25 °C
Refractive Index	n20/D 1.597
UNSPSC	12352112

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