Bis(3,5-dimethyl-4-methoxyphenyl)chlorophosphine
ALDRICH/710385 - 95%
CAS Number: 136802-85-2
Empirical Formula (Hill Notation): C18H22ClO2P
Molecular Weight: 336.79
MDL Number: MFCD01630810
Linear Formula: C18H22ClO2P
Product Type: Chemical
| assay | 95% |
| density | 1.141 g/cm3 at 25 °C |
| form | liquid |
| functional group | phosphine |
| InChI | 1S/C18H22ClO2P/c1-11-7-15 |
| InChI key | JWCZKGYRAINWJA-UHFFFAOYSA |
| Quality Level | 100 ![]() |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: ligand | |
| refractive index | n |
| SMILES string | COc1c(C)cc(cc1C)P(Cl)c2cc |
| Application: | Reactant for: • Asymmetric organocatalytic electrophilic phosphination • Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands • Synthesis of ferrocene-based chiral diphosphines • Alcoholysis of phosphane-boranes • Asymmetric hydrogenations of bifep-type biferrocenes |
| Packaging: | 1 g in glass bottle |
| Symbol | GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-43-45 |
| RIDADR | UN 1760 8 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 95% |
| Density | 1.141 g/cm3 at 25 °C |
| Refractive Index | n |
| UNSPSC | 12352112 |


