Sodium diformylamide
ALDRICH/71494 - ≥97.0% (NT)
Synonym: Diformylimide sodium salt
CAS Number: 18197-26-7
Empirical Formula (Hill Notation): C2H2NNaO2
Molecular Weight: 95.03
MDL Number: MFCD00145302
Linear Formula: (HCO)2NNa
Product Type: Chemical
assay | ≥97.0% (NT) |
form | powder |
InChI | 1S/C2H3NO2.Na/c4-1-3-2-5; |
InChI key | QJXDSDLNUKLDBP-UHFFFAOYSA |
SMILES string | [Na+].O=C[N-]C=O |
Application: | Reactant for preparation of: • Functionalized condensed benzazoles • α-ketoheterocycles as inhibitors of Leishmania mexicana cysteine protease CPB • INOS inhibitor PHA-399733 via Bucherer-Bergs hydantoin synthesis • Antibiotic resistance (C β-lactamase AmpC ) inhibitor analogues, with improved cell permeability properties • BINOL- and H8-BINOL-based aryl phosphites as ligands in palladium-catalyzed asymmetric allylation and amination reactions • Precursors of αVβ3 integrin antagonists |
Other Notes: | Modified Gabriel reagent for the synthesis of amines; mild hydrolysis to release the amine |
Packaging: | 25, 50 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥97.0% (NT) |
UNSPSC | 12352111 |