(S)-2-[(Diphenylphosphino)methyl]pyrrolidine

ALDRICH/716715

CAS Number: 60261-46-3
Empirical Formula (Hill Notation): C₁₇H₂₀NP
Molecular Weight: 269.32
MDL Number: MFCD16621443
Linear Formula: C₁₇H₂₀NP
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-716715-250MG	250 mg	$92.40 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

density	1.043 g/mL at 25 °C
form	liquid
InChI	1S/C17H20NP/c1-3-9-16(10-4-1)19(14-15-8-7-13-18-15)17-11-5-2-6-12-17/h1-6,9-12,15,18H,7-8,13-14H2/t15-/m0/s1
InChI key	IWRBGJKCDORZHK-HNNXBMFYSA-N
optical activity	[α]22/D −24.0°, c = 0.5 in ethanol
refractive index	n20/D 1.614
SMILES string	C1CN[C@@H](C1)CP(c2ccccc2)c3ccccc3

Application:	Catalytic ligand in: • Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans • Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal
Legal Information:	Sold under license from Kanata Chemical Technologies Inc. for research purposes only.
Packaging:	250 mg in amber glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	> 230.0 °F - closed cup
Flash Point(C)	> 110 °C - closed cup

Density	1.043 g/mL at 25 °C
Refractive Index	n20/D 1.614
UNSPSC	12352005

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