Manganese(II) chloride bis(lithium chloride) complex solution
ALDRICH/718114 - 0.5 M in THF, density: 0.956 g/mL at 25 °C
Synonym: Lithium tetrachloromanganate(II) solution; Lithium chloromanganate(II); Lithium manganese chloride; Manganese(II) chloride bis(lithium chloride) complex solution
CAS Number: 57384-24-4
Empirical Formula (Hill Notation): Cl4Li2Mn
Molecular Weight: 210.63
MDL Number: MFCD00192059
Linear Formula: Li2MnCl4
Product Type: Chemical
| concentration | 0.5 M in THF |
| density | 0.956 g/mL at 25 °C |
| form | liquid |
| InChI | 1S/4ClH.2Li.Mn/h4*1H;;;/q |
| InChI key | VJOUQNFWQPCDPE-UHFFFAOYSA |
| Quality Level | 100  |
| reaction suitability | core: manganese |
| reagent type: catalyst | |
| SMILES string | [Li+].[Li+].Cl[Mn--](Cl)( |
| Application: | Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant Reactant for: • Transmetalation reactions • Nickel-imidazolium carbene-catalyzed coupling reactions Reagent for the preparation of Rieke manganese |
| Packaging: | 100 mL in Sure/Seal™ |
| Symbol |    GHS02,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225 - H302 - H315 - H319 - H335 - H351 |
| Precautionary statements | P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235 |
| Hazard Codes | F,Xn |
| Risk Statements | 11-19-36/37-40 |
| Safety Statements | 16-26-36/37 |
| RIDADR | UN 2056 3 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 1.4 °F - closed cup |
| Flash Point(C) | -17.0 °C - closed cup |
| Supplemental Hazard Statements | EUH019 |
| Density | 0.956 g/mL at 25 °C |
| UNSPSC | 12161600 |