Lithium diisobutyl-tert-butoxyaluminum hydride solution

ALDRICH/718386 - 0.25 M in THF/hexanes

Synonym: LDBBA

CAS Number: 77299-63-9
Empirical Formula (Hill Notation): C₁₂H₂₈AlLiO
Molecular Weight: 222.27
MDL Number: MFCD16621454
Linear Formula: C₁₂H₂₈AlLiO
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-718386-25ML	25 mL	$176.00 1/EA		Add To Favorites
45-718386-100ML	100 mL	$478.00 1/EA		Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.25 M in THF/hexanes
density	0.795 g/mL at 25 °C
form	liquid
InChI	1S/C4H9O.2C4H9.Al.Li.H/c1-4(2,3)5;21-4(2)3;;;/h1-3H3;24H,1H2,2-3H3;;;/q-1;;;;+1;
InChI key	HNIYOHKCLUHKGY-UHFFFAOYSA-N
Quality Level	100
reaction suitability	reagent type: reductant
SMILES string	[Li+].CC(C)C[AlH-](CC(C)C)OC(C)(C)C
storage temp.	2-8°C

Application:	Lithiumdiisobutyl-tert-butoxyaluminum hydride solution can be used as a reducing agent for the reduction of: • Aromatic and aliphatic nitriles to aldehydes. • Aromatic and aliphatic esters to aldehydes. • Tertiary amides to aldehydes.
Packaging:	25, 100 mL in Sure/Seal™

Symbol	GHS02,GHS07,GHS08,GHS09
Signal word	Danger
Hazard statements	H225 - H261 - H304 - H315 - H319 - H335 - H336 - H351 - H361f - H411
Precautionary statements	P210 - P231 + P232 - P273 - P301 + P310 - P303 + P361 + P353 - P331
Hazard Codes	F,Xn,N
Risk Statements	15-19-36/37/38-40-48/20-51/53-62-65-67
Safety Statements	26-36/37-43-61-62
RIDADR	UN 3399BC 4.3(3) / PGII
WGK Germany	WGK 3
Supplemental Hazard Statements	EUH019

Density	0.795 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352103

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