BrettPhos Pd G1, Methyl t-Butyl Ether Adduct

ALDRICH/718750 - may contain up to 1 mole equivalent of MTBE, 97%

Synonym: (BrettPhos) palladium(II) phenethylamine chloride; BrettPhos Palladacycle; BrettPhos precatalyst; Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2′,4′, 6′-triisopropyl-1,1′-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)

Empirical Formula (Hill Notation): C₄₃H₆₃ClNO₂PPd
Molecular Weight: 798.81
Linear Formula: C₄₃H₆₃ClNO₂PPd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-718750-100MG	100 mg	$90.10 1/EA	Add To Favorites
45-718750-1G	1 g	$549.00 1/EA	Add To Favorites
45-718750-5G	5 g	$1490.00 1/EA	Add To Favorites

BrettPhos Palladacycle

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Properties
Descriptions
Safety Info.
Basic Data

assay	97%
feature	generation 1
form	solid
functional group	phosphine
InChI	1S/C35H53O2P.C8H10N.C5H12O.ClH.Pd/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;9-7-6-8-4-2-1-3-5-8;1-5(2,3)6-4;;/h19-25,27-28H,9-18H2,1-8H3;1-4H,6-7,9H2;1-4H3;1H;/q;;;;+1/p-1
InChI key	OWHWOTGYDWMPCA-UHFFFAOYSA-M
mp	198-204 °C
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	COC(C)(C)C.NCCc1ccccc1[Pd]Cl.COc2ccc(OC)c(c2P(C3CCCCC3)C4CCCCC4)-c5c(cc(cc5C(C)C)C(C)C)C(C)C

Application:	Application Guide for Palladium Catalyzed Cross-Coupling Reactions Catalyst for: • C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines • Amination reaction • N-arylation of aminophenols
General description:	BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to −40 °C, and can be used in a variety of cross-coupling protocols.
Packaging:	1, 5 g in glass bottle
Packaging:	100 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P261 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	198-204 °C
UNSPSC	12161600

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