Palladium(II) acetate, recrystallized
ALDRICH/720070 - 97%
Synonym: Pd(OAc)2
CAS Number: 3375-31-3
Empirical Formula (Hill Notation): C4H6O4Pd
Molecular Weight: 224.51
EC Number: 222-164-4
MDL Number: MFCD00012453
Linear Formula: Pd(OCOCH3)2
Product Type: Chemical
| assay | 97% |
| form | powder |
| InChI | 1S/2C2H4O2.Pd/c2*1-2(3)4; |
| InChI key | YJVFFLUZDVXJQI-UHFFFAOYSA |
| mp | 227-231 °C |
| Quality Level | 100  |
| reaction suitability | core: palladium |
| reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: catalyst | |
| SMILES string | CC(=O)O[Pd]OC(C)=O |
| Application: | Palladium(II) acetate, recrystallized can be used as a catalyst: • In Stille cross-coupling reaction between benzylic halides and aryl tributyltin to synthesize diarylmethane derivatives in the presence of phosphine ligand. • For the α-arylation of ketones with aryl halides to synthesize arylmethyl ketones in the presence of n-butylbis(1-adamantyl)-ph • In Suzuki-Miyaura cross-coupling reaction between aryl bromides and aryl boronic acids to synthesize biaryl derivatives in the presence of phosphane ligand. • In Buchwald-Hartwig amination reaction between aryl chlorides and anilines to synthesize arylated anilines in the presence of N-heterocyclic carbene ligand. |
| General description: | Palladium(II)acetate, recrystallized, is commonly used as a catalyst in cross-coupling reactions. Prominent applications include the Buchwald-Hartwigamination reaction, Heck reaction, Suzuki coupling, Stille coupling, Sonogashira coupling, and Negishi coupling reactions. |
| Packaging: | 1 g in glass bottle |
| Symbol |     GHS05,GHS07,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H317 - H318 - H361d - H410 |
| Precautionary statements | P202 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313 |
| Hazard Codes | C |
| Risk Statements | 35 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 227-231 °C |
| UNSPSC | 12161600 |