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Palladium(π-cinnamyl) chloride dimer

ALDRICH/720526 - 97%

Synonym: Bis[cinnamyl palladium(II) chloride]; Palladium(1-phenylallyl)chloride dimer; [(Cinnamyl)PdCl]2; [Pd(1-phenylallyl)Cl]2

CAS Number: 12131-44-1
Empirical Formula (Hill Notation): C18H18Cl2Pd2
Molecular Weight: 518.08
MDL Number: MFCD16621470
Linear Formula: C18H18Cl2Pd2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-720526-1G 1 g
 $163.00
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assay 97%
form solid
InChI 1S/2C9H9.2ClH.2Pd/c2*1-2-6-9-7-4-3-5-8-9;;;;/h2*2-8H,1H2;2*1H;;/q;;;;2*+1/p-2
InChI key SHWAPUDBEQXXLQ-UHFFFAOYSA-L
mp 218-220 °C
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Cross Couplings
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string Cl[Pd].Cl[Pd].[CH2][CH][CH]c1ccccc1.[CH2][CH][CH]c2ccccc2
storage temp. 2-8°C
Application: Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
• Ammonia cross-coupling reactions to synthesize arylamines.
• Conversion of aryl triflates to fluorides.

It can also be used as a source of palladium in the asymmetric α-arylation of amides.
Packaging: 1 g in glass bottle
Hazard Codes T
Risk Statements 23-43
Safety Statements 22-35-36/37-45
RIDADR UN 2811 6.1 / PGIII
WGK Germany WGK 3
Purity 97%
mp 218-220 °C
Storage Temp. 2-8°C
UNSPSC 12161600

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