2-(Trimethylsilyl)-2,3-pentadiene
ALDRICH/720631
Synonym: 1,3-
CAS Number: 77494-35-0
Empirical Formula (Hill Notation): C8H16Si
Molecular Weight: 140.30
MDL Number: MFCD17171289
Linear Formula: C8H16Si
Product Type: Chemical
| density | 0.746 g/mL at 25 °C |
| form | liquid |
| InChI | 1S/C8H16Si/c1-6-7-8(2)9(3 |
| InChI key | JGOGDIIEKVYPFO-UHFFFAOYSA |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | CC=C=C(C)[Si](C)(C)C |
| storage temp. | −20°C |
| Application: | Reactant for: • Oxidative cyclization with chlorine to give chloro- and acetoxybenziodoxaboroles and a self-assembled tetrameric macrocyclic structure • Preparation of allylic alcohols or enone derivatives using boronic acid as catalyst Catalyst for: • Preparation of acylsulfoximines via N-acylation of sulfoximines with aliphatic acids • Direct amide bond formation • Regioselective preparation of substituted triazole derivatives via dipolar cycloaddition of unsaturated carboxylic acids with azides |
| Packaging: | 500 mg in glass bottle |
| Symbol |  GHS02 |
| Signal word | Danger |
| Hazard statements | H225 |
| Precautionary statements | P210 |
| Hazard Codes | F |
| Risk Statements | 11 |
| Safety Statements | 16 |
| RIDADR | UN 1993BF 3 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 15.1 °F |
| Flash Point(C) | -9.4 °C |
| Density | 0.746 g/mL at 25 °C |
| Refractive Index | n |
| Storage Temp. | −20°C |
| UNSPSC | 12352100 |