Bis(4-methylphenyl)iodonium hexafluorophosphate

ALDRICH/726192 - 98%

Synonym: Bis(p-tolyl)iodonium hexafluorophosphate

CAS Number: 60565-88-0
Empirical Formula (Hill Notation): C₁₄H₁₄F₆IP
Molecular Weight: 454.13
EC Number: 262-301-5
MDL Number: MFCD06656584
Linear Formula: C₁₄H₁₄F₆IP
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-726192-5G	5 g	$246.00 1/EA		Add To Favorites
45-726192-25G	25 g	$948.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥97.5% (TLC)
	98%
form	solid
InChI	1S/C14H14I.F6P/c1-11-3-7-13(8-4-11)15-14-9-5-12(2)6-10-14;1-7(2,3,4,5)6/h3-10H,1-2H3;/q+1;-1
InChI key	LHLVGWWCRPPKBC-UHFFFAOYSA-N
SMILES string	F[P-](F)(F)(F)(F)F.Cc1ccc([I+]c2ccc(C)cc2)cc1

Application:	Covalent Functionalisation of Few-Layer Black Phosphorus using Aryl Iodonium Salts and Comparison to Diazonium Modified Black Phosphorus: Explores the functionalization of black phosphorus using bis(4-methylphenyl)iodonium hexafluorophosphate and compares it to diazonium modification (M Van Druenen, 2019 ). Iodonium sulfonates as high‐performance coinitiators and additives for CQ‐based systems: Toward aromatic amine‐free photoinitiating systems: Examines the effectiveness of iodonium sulfonates and bis(4-methylphenyl)iodonium hexafluorophosphate in CQ-based photoinitiating systems (J Kirschner et al., 2019 ). Thiophene-substituted phenothiazine-based photosensitisers for radical and cationic photopolymerization reactions under visible laser beams (405 and 455 nm): Studies the use of thiophene-substituted phenothiazine in combination with bis(4-methylphenyl)iodonium hexafluorophosphate for effective photopolymerization (P Chao et al., 2016 ).
General description:	Bis(4-methylphenyl)iodonium hexafluorophosphate is a white powder. It melts at 175-180 °C and shows an UV absorption peak at 267nm. 1
Packaging:	5, 25 g in glass bottle

Symbol	GHS05
Signal word	Danger
Hazard statements	H314
Precautionary statements	P280 - P305 + P351 + P338 - P310
Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45
RIDADR	UN 1759 8 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥97.5% (TLC); 98%
UNSPSC	12352300

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