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Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride

ALDRICH/728551 - ≥97% (AT)

Synonym: Chloro[N2-[2-(dimethylamino-κN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-κN1,κN2]-nickel; Nickamine

CAS Number: 1033772-47-2
Empirical Formula (Hill Notation): C16H20ClN3Ni
Molecular Weight: 348.50
MDL Number: MFCD17015253
Linear Formula: C16H20ClN3Ni
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-728551-100MG 100 mg
 $589.00
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45-728551-500MG 500 mg
 $1350.00
1/EA		 Add To Favorites

 

assay ≥97% (AT)
form lumps
InChI 1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
InChI key IRLHVNUEEKJBEL-UHFFFAOYSA-M
Quality Level 200 
reaction suitability core: nickel
  reagent type: catalyst
SMILES string CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
Application: Catalyst for:
• Alkyl-alkyl Kumada coupling of secondary alkyl halides
• Direct alkylation of heterocyclic C-H bonds
• Sonogashira coupling of nonactivated alkyl halides
• Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles

Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
Packaging: 100, 500 mg in glass bottle
Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥97% (AT)
UNSPSC 12161600

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