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JackiePhos

ALDRICH/731013 - 95%

Synonym: 2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-3,6-dimethoxy -2′,4′,6′-triisopropyl-1,1′-biphenyl; Bis(3,5-bis(trifluoromethyl)phenyl)(2′,4′,6′- triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine

CAS Number: 1160861-60-8
Empirical Formula (Hill Notation): C39H37F12O2P
Molecular Weight: 796.66
MDL Number: MFCD17015286
Linear Formula: C39H37F12O2P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-731013-100MG 100 mg
 $90.10
1/EA		 Add To Favorites
45-731013-250MG 250 mg
 $214.00
1/EA		 Add To Favorites
45-731013-1G 1 g
 $792.00
1/EA		 Add To Favorites

 

assay 95%
form solid
functional group phosphine
InChI 1S/C39H37F12O2P/c1-19(2)22-11-29(20(3)4)33(30(12-22)21(5)6)34-31(52-7)9-10-32(53-8)35(34)54(27-15-23(36(40,41)42)13-24(16-27)37(43,44)45)28-17-25(38(46,47)48)14-26(18-28)39(49,50)51/h9-21H,1-8H3
InChI key KYTUFIMHJNRPLC-UHFFFAOYSA-N
mp 186-190 °C
reaction suitability reaction type: Cross Couplings
  reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reagent type: ligand
reaction type: C-X Bond Formation
SMILES string COc1ccc(OC)c(c1P(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F)-c4c(cc(cc4C(C)C)C(C)C)C(C)C
Application: Catalyst for N-Arylation reactions

Buchwald Phosphine Ligands for chemical Synthesis 
Application: JackiePhos is a Buchwald′s phosphine ligand which can be used for the:
• glycosyl cross-coupling reaction of diaryliodonium triflates with anomeric stannanes to synthesize C-glycosides.
• synthesis of gold-based catalyst complexes such as [Au(CH3CN)(JackiePhos)][SbF6] and [(JackiePhos)AuCl.
• acylation of alkylcarbastannatranes.
• synthesis of cyclic guanidines or cyclic ureas bearing dialkylaminomethyl groups in combination with Pd(acac)2 as a catalyst.
Packaging: 1 g in glass bottle
Packaging: 100, 250 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 186-190 °C
UNSPSC 12352112

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