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(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

ALDRICH/731382

Synonym: Fe(R,R-PDP); Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate; White-Chen catalyst; [Fe(R,R-PDP)(CH3CN)2](SbF6)2

CAS Number: 1361315-26-5
Empirical Formula (Hill Notation): C24H32F12FeN6Sb2
Molecular Weight: 931.90
MDL Number: MFCD16038114
Linear Formula: C24H32F12FeN6Sb2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-731382-500MG 500 mg
 $412.00
1/EA		 Add To Favorites
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

form powder
greener alternative category  , Aligned 
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1
InChI key XUNWHBGEOCZDBX-QSKJABRXSA-B
mp 215-226 °C
reaction suitability core: iron
  reagent type: catalyst
SMILES string [Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4
sustainability Greener Alternative Product
Application: Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation 
General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
Packaging: 100, 500 mg in glass bottle
mp 215-226 °C
UNSPSC 12161600

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