Pd-PEPPSI^™-IPent catalyst

ALDRICH/732117 - ≥95%

Synonym: Dichloro[1,3-bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II); [1,3-Bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)dichloropalladium(II); [1,3-Bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride

CAS Number: 1158652-41-5
Empirical Formula (Hill Notation): C₄₀H₅₆Cl₃N₃Pd
Molecular Weight: 791.67
MDL Number: MFCD34166665
Linear Formula: C₄₀H₅₆Cl₃N₃Pd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-732117-250MG	250 mg	$219.00 1/EA	Add To Favorites
45-732117-1G	1 g	$439.00 1/EA	Add To Favorites
45-732117-5G	5 g	$1980.00 1/EA	Add To Favorites
45-732117-50G	50 g	$17560.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 732117-1G

Properties
Descriptions
Safety Info.
Basic Data

assay	≥95%
form	solid
InChI	1S/C35H52N2.C5H4ClN.2ClH.Pd/c1-9-26(10-2)30-19-17-20-31(27(11-3)12-4)34(30)36-23-24-37(25-36)35-32(28(13-5)14-6)21-18-22-33(35)29(15-7)16-8;6-5-2-1-3-7-4-5;;;/h17-24,26-29H,9-16H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2
InChI key	BCXSKTXOKALLAZ-UHFFFAOYSA-L
mp	195-201 °C
Quality Level	200
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst
SMILES string	Clc1cccnc1.CCC(CC)c2cccc(C(CC)CC)c2N3C=CN(c4c(cccc4C(CC)CC)C(CC)CC)C3=[Pd](/Cl)Cl
storage temp.	−20°C

Application:	• Catalyst for Stille coupling reaction (eq. 1) • Catalyst for Negishi coupling reaction (eq. 2) • Catalyst for Suzuki coupling reaction (eq. 3) For small scale and high throughput uses, product is also available as ChemBeads (928399 )
Application:	Application Guide for Palladium Catalyzed Cross-Coupling Reactions Cross-Coupling, Amination and Heck Transformation using PEPPSI Catalysts
General description:	Pd-PEPPSI^™-IPent catalyst is a palladium-based catalyst used in cross-coupling reactions to form C-N and C- C bonds.
Legal Information:	Patented, U.S. Pat. No. 7,250,510. Sold under an exclusive license from Total Synthesis Ltd.
Legal Information:	PEPPSI is a trademark of Total Synthesis Ltd.
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332
Precautionary statements	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	36/37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥95%
mp	195-201 °C
Storage Temp.	−20°C
UNSPSC	12161600

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