Pd-PEPPSI^™-IPent catalyst

ALDRICH/732117 - ≥95%

Synonym: Dichloro[1,3-bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II); [1,3-Bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)dichloropalladium(II); [1,3-Bis(2,6-Di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride

CAS Number: 1158652-41-5
Empirical Formula (Hill Notation): C₄₀H₅₆Cl₃N₃Pd
Molecular Weight: 791.67
Linear Formula: C₄₀H₅₆Cl₃N₃Pd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-732117-250MG	250 mg	$206.00 1/EA	Add To Favorites
45-732117-1G	1 g	$412.00 1/EA	Add To Favorites
45-732117-5G	5 g	$1860.00 1/EA	Add To Favorites
45-732117-50G	50 g	$16490.00 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

assay	≥95%
form	solid
InChI	1S/C35H52N2.C5H4ClN.2ClH.Pd/c1-9-26(10-2)30-19-17-20-31(27(11-3)12-4)34(30)36-23-24-37(25-36)35-32(28(13-5)14-6)21-18-22-33(35)29(15-7)16-8;6-5-2-1-3-7-4-5;;;/h17-24,26-29H,9-16H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2
InChI key	BCXSKTXOKALLAZ-UHFFFAOYSA-L
mp	195-201 °C
Quality Level	200
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst
SMILES string	Clc1cccnc1.CCC(CC)c2cccc(C(CC)CC)c2N3C=CN(c4c(cccc4C(CC)CC)C(CC)CC)C3=[Pd](/Cl)Cl
storage temp.	−20°C

Application:	• Catalyst for Stille coupling reaction (eq. 1) • Catalyst for Negishi coupling reaction (eq. 2) • Catalyst for Suzuki coupling reaction (eq. 3) For small scale and high throughput uses, product is also available as ChemBeads (928399 )
Application:	Application Guide for Palladium Catalyzed Cross-Coupling Reactions Cross-Coupling, Amination and Heck Transformation using PEPPSI Catalysts
General description:	Pd-PEPPSI^™-IPent catalyst is a palladium-based catalyst used in cross-coupling reactions to form C-N and C- C bonds.
Legal Information:	Patented, U.S. Pat. No. 7,250,510. Sold under an exclusive license from Total Synthesis Ltd.
Legal Information:	PEPPSI is a trademark of Total Synthesis Ltd.
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332
Precautionary statements	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	36/37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥95%
mp	195-201 °C
Storage Temp.	−20°C
UNSPSC	12161600

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