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Tetrakis(dimethylsulfoxide)dichlororuthenium(II)

ALDRICH/733210 - 96%

Synonym: Dichlorotetrakis(dimethyl sulfoxide)ruthenium

CAS Number: 89395-66-4
Empirical Formula (Hill Notation): C8H24Cl2O4RuS4
Molecular Weight: 484.51
MDL Number: MFCD00050955
Linear Formula: C8H24Cl2O4RuS4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-733210-1G 1 g
 $137.00
1/EA		 Add To Favorites
45-733210-5G 5 g
 $506.00
1/EA		 Add To Favorites

 

assay 96%
form solid
InChI 1S/4C2H6OS.2ClH.Ru/c4*1-4(2)3;;;/h4*1-2H3;2*1H;/q;;;;;;+2/p-2
InChI key UMJDEUKQHKMAOI-UHFFFAOYSA-L
mp 192-198 °C
Quality Level 100 
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string O=S(C)C.O=S(C)C.Cl[Ru](Cl)O=S(C)C.O=S(C)C
Application: RuCl2(dmso)4 can be used as a catalyst for:
• The β-alkylation of secondary alcohols via hydrogen auto-transfer process.
• The oxidation of thioethers (S) to sulfoxides by N-methylmorpholine N-oxide (NMO).

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) can be used as a precursor in the synthesis of Ru(II)-MEPE (metallo-supramolecular polyelectrolytes) complex, which is used to prepare electrochromic organic-metallic hybrid polymers.
General description: Tetrakis(dimethylsulfoxide)dichlororuthenium(II), [RuCl2(dmso)4] is an organoruthenium compound. It is used as a homogeneous catalyst in organic synthesis.

Tetrakis(dimethylsulfoxide)dichlororuthenium(II) (Ru(DMSO)4Cl2) is a coordination complex generally used as a catalyst in various reactions. In addition, it is also used as a precursor in the synthesis of other ruthenium complexes.
Packaging: 1, 5 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 96%
mp 192-198 °C
UNSPSC 12161600

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