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Tetrakis(pyridine)copper(II) triflate

ALDRICH/734527 - 95%

Synonym: [Cu(OTf)2(py)4]; Cu(pyridine)4(OTf)2; Tetrakis(pyridine)copper(II) bis(trifluoromethanesulfonate)

CAS Number: 113110-58-0
Empirical Formula (Hill Notation): C22H20CuF6N4O6S2
Molecular Weight: 678.08
MDL Number: MFCD19105629
Linear Formula: C22H20CuF6N4O6S2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-734527-250MG 250 mg
 $119.00
1/EA		 Add To Favorites
45-734527-1G 1 g
 $331.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 734527-1G

 

assay 95%
form crystals
InChI 1S/4C5H5N.2CHF3O3S.Cu/c4*1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;/h4*1-5H;2*(H,5,6,7);/q;;;;;;+2/p-2
InChI key DOUMBTAZXRQKGF-UHFFFAOYSA-L
mp 190-194 °C
Quality Level 100 
reaction suitability core: copper
  reagent type: catalyst
SMILES string c1ccncc1.c2ccncc2.c3ccncc3.c4ccncc4.FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F
storage temp. −20°C
Application: Tetrakis(pyridine)copper(II) triflate can be used to catalyze:
• Intra and intermolecular aziridination of allylic carbamates and styrenes.
• 18F-fluorination of aryl boronic esters to generate fluroarenes applicable as radiotracers.
• Nucleophilic radiobromination of aryl borons with a radiobromide ion applicable in the preparation of radiobrominated pharmaceuticals.
Application: Tetrakis(pyridine)copper(II) triflate [Cu(OTf)2(py)4] is a general copper-based catalyst. It is commonly used to catalyze copper-mediated radiofluorination of arenes and heteroarene. It is also employed in C(sp3)-H functionalization/cyclisation of 2-amino-N,N-dialkylbenzamides to synthesize 2,3-disubstituted-4(3H)-quinazolinones.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
Purity 95%
mp 190-194 °C
Storage Temp. −20°C
UNSPSC 12161600

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