Synonym: (1R,1′R)- 1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS); Mandyphos SL-M004-1
CAS Number: 494227-37-1
Empirical Formula (Hill Notation): C64H74FeN2O4P2
Molecular Weight: 1053.08
MDL Number: MFCD04117704
Linear Formula: C64H74FeN2O4P2
Product Type: Chemical
| assay |
≥97% |
| form |
powder |
| InChI |
1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/t2*30-;/m11./s1 |
| InChI key |
HEJIDMKBSDYNOY-LJXMUBMNSA-N |
| optical purity |
ee: ≥99% |
| SMILES string |
[Fe].COc1c(C)cc(cc1C)P([C]2[CH][CH][CH][C]2[C@H](N(C)C)c3ccccc3)c4cc(C)c(OC)c(C)c4.COc5c(C)cc(cc5C)P([C]6[CH][CH][CH][C]6[C@H](N(C)C)c7ccccc7)c8cc(C)c(OC)c(C)c8 |
| Application: |
It may be used as a chiral ligand in the rhodium complex-catalyzed hydrogenation reaction, a key step during the synthesis of argatroban. |
| General description: |
Mandyphos SL-M004-1 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family. |
| Other Notes: |
sold in collaboration with Solvias AG |
| Packaging: |
1, 5 g in glass bottle |
| Packaging: |
100, 500 mg in glass bottle |
| Packaging: |
Bottomless glass bottle. Contents are inside inserted fused cone. |
| RIDADR |
NONH for all modes of transport |
| WGK Germany |
WGK 3 |
| Flash Point(F) |
Not applicable |
| Flash Point(C) |
Not applicable |
| Purity |
≥97% |
| UNSPSC |
12352005 |
