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Copper(I) bromide

ALDRICH/735906 - AnhydroBeads, -10 mesh, 99.99% trace metals basis

Synonym: Cuprous bromide

CAS Number: 7787-70-4
Empirical Formula (Hill Notation): BrCu
Molecular Weight: 143.45
EC Number: 232-131-6
MDL Number: MFCD00010969
Linear Formula: CuBr
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-735906-25G 25 g
$262.00
1/EA
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application(s) battery manufacturing
assay 99.99% trace metals basis
density 4.71 g/mL at 25 °C (lit.)
form beads
impurities ≤150.0 ppm Trace Metal Analysis
InChI 1S/BrH.Cu/h1H;/q;+1/p-1
InChI key NKNDPYCGAZPOFS-UHFFFAOYSA-M
mp 504 °C (lit.)
particle size -10 mesh
product line AnhydroBeads
SMILES string [Cu]Br
Application: Some reported applications of copper bromide are:
• catalyst in cross coupling reactions.
• co-catalyst in Sonogashira coupling.
• Lewis acid in enantioselective addition of alkynes.
• reducing agent, when complexed by three molecules of pyridine initiators for the controlled polymerization of styrene, methyl acrylate and methyl methacrylate.

Reductive homocoupling of α-bromo- α- chlorocarboxylates to dimethyl α, α′ dichlorosuccinate derivatives in presence of CuBr/LiOCH3 in methanol has been reported.
General description: Cuprous bromide may be prepared by the reduction of cupric bromide or CuSO4-NaBr. In the molten state, it is grayish brown /greenish brown in color.
Legal Information: AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC
Packaging: 25 g in glass bottle
Purity 99.99% trace metals basis
mp 504 °C (lit.)
Density 4.71 g/mL at 25 °C (lit.)
UNSPSC 12352302

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