Mesitylcopper(I)

ALDRICH/736627

Synonym: (2,4,6-Trimethylphenyl)copper

CAS Number: 75732-01-3
Empirical Formula (Hill Notation): C₉H₁₁Cu
Molecular Weight: 182.73
MDL Number: MFCD00015622
Linear Formula: C₉H₁₁Cu
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-736627-1G	1 g	$300.00 1/EA		Add To Favorites
45-736627-5G	5 g	$1240.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
InChI	1S/C9H11.Cu/c1-7-4-8(2)6-9(3)5-7;/h4-5H,1-3H3;
InChI key	BBUKMFLZOHNUQU-UHFFFAOYSA-N
mp	184-191 °C
reaction suitability	core: copper
	reagent type: catalyst
SMILES string	Cc1cc(C)c([Cu])c(C)c1
storage temp.	2-8°C

Application:	Mesitylcopper(I) is can be used to synthesize: • Homo and heteroleptic copper(I) complexes such as Cu(I) alkoxides, siloxides, phosphates, amides, and phosphides. • Biorelevant copper(I) complexes as biomimetic model compounds. • Copper nanoparticles from stabilizing primary amines. It can also be used as a selective mesityl group transfer reagent in stoichiometric C−C and C−heteroatom bond-forming reactions.
General description:	Mesitylcopper(I) is a thermally stable and highly soluble organocopper compound, which is commonly used as a metalation reagent in organic synthesis. In mixed lithium cuprate reagents, mesitylcopper serves as a useful ″holding group″. It is very sensitive to moisture and air therefore reactions must be carried out under anhydrous conditions.
Packaging:	1, 5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	36/37/39
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	184-191 °C
Storage Temp.	2-8°C
UNSPSC	12161600

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