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Tris(triethylsilyl)silane

ALDRICH/736856

Synonym: 1,1,1,3,3,3-Hexaethyl-2-(triethylsilyl)trisilane; 1,1,1,3,3,3-Hexaethyl-2-(triethylsilyl)trisilane; 3,4,5-Trisilaheptane, 3,3,5,5-tetraethyl-4-(triethylsilyl)

CAS Number: 25436-74-2
Empirical Formula (Hill Notation): C18H46Si4
Molecular Weight: 374.90
MDL Number: MFCD19053177
Linear Formula: C18H46Si4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-736856-5G 5 g
 $586.00
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density 0.887 g/mL at 25 °C
form liquid
InChI 1S/C18H46Si4/c1-10-20(11-2,12-3)19(21(13-4,14-5)15-6)22(16-7,17-8)18-9/h19H,10-18H2,1-9H3
InChI key WNGZMQFMMHZKBG-UHFFFAOYSA-N
reaction suitability reagent type: reductant
refractive index n20/D 1.526
SMILES string CC[Si](CC)(CC)[SiH]([Si](CC)(CC)CC)[Si](CC)(CC)CC
storage temp. 2-8°C
Application: Tris(triethylsilyl)silane can be incorporated as a directing group for various regio- and stereo-selective reactions. Hydrogen abstraction from tris(triethylsilyl)silane yields highly stable silyl radical.
Application: Tris(triethylsilyl)silane can be used as a hydrogen atom donor reagent in chemical synthesis due to its weak Si-H bond. Hydrogen abstraction from tris(triethylsilyl)silane yields a highly stable silyl radical.
It can be used as a reagent:
• In the radical coupling reaction to generate C-C bonds from alkyl-halogen compounds using iridium and nickel catalysts.
• To synthesize α-arylated product via cross-electrophile coupling reaction between α-chloro carbonyl and aryl bromide in the presence of nickel and iridium catalysts.
Packaging: 5 g in glass bottle
Density 0.887 g/mL at 25 °C
Refractive Index n20/D 1.526
Storage Temp. 2-8°C
UNSPSC 12352001

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