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Ru-MACHO®

ALDRICH/739103

Synonym: Carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethyl]amino}ruthenium(II); {Bis[2-(diphenylphosphino)ethyl]amine}carboynlchlorohydridoruthenium(II)

CAS Number: 1295649-40-9
Empirical Formula (Hill Notation): C29H30ClNOP2Ru
Molecular Weight: 607.03
Linear Formula: C29H30ClNOP2Ru
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-739103-250MG 250 mg
 $75.10
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45-739103-1G 1 g
 $286.00
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45-739103-5G 5 g
 $478.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 739103-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 739103-5G

 

form solid
InChI 1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1
InChI key GQFWSAKCCNATEV-UHFFFAOYSA-M
mp 260-290 °C
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4
Application: <ul><BR/><li><strong>Dehydrogenati<WBR>ve Intramolecular Macrolactonization:</stro<WBR>ng> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (<A class="External" onClick="cmCreateManualPageviewTag('doi.org - 739103 ALDRICH', 'EXTERNAL LINKS', 'https://doi.org/10.1021/acs.orglett.2c01617', window.location);" rel="nofollow" href="https://doi.org/10.1021/acs.orglett.2c01617">Jamdade et al., 2022</A><img src="https://krackeler.com/images/pixel.png">).</li><BR/><li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (<A class="External" onClick="cmCreateManualPageviewTag('doi.org - 739103 ALDRICH', 'EXTERNAL LINKS', 'https://doi.org/10.1002/anie.202110910', window.location);" rel="nofollow" href="https://doi.org/10.1002/anie.202110910">Kaithal et al., 2021</A><img src="https://krackeler.com/images/pixel.png">).</li><BR/><li><strong>Precapture and Hydrogenation of CO<SUB>2</SUB>:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO<SUB>2</SUB> into methanol, underscoring the catalyst′s potential in sustainable chemical processes (<A class="External" onClick="cmCreateManualPageviewTag('doi.org - 739103 ALDRICH', 'EXTERNAL LINKS', 'https://doi.org/10.1002/open.202300060', window.location);" rel="nofollow" href="https://doi.org/10.1002/open.202300060">Szego et al., 2023</A><img src="https://krackeler.com/images/pixel.png">).</li><BR/><li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (<A class="External" onClick="cmCreateManualPageviewTag('doi.org - 739103 ALDRICH', 'EXTERNAL LINKS', 'https://doi.org/10.1039/d3cc05239g', window.location);" rel="nofollow" href="https://doi.org/10.1039/d3cc05239g">Johnson et al., 2024</A><img src="https://krackeler.com/images/pixel.png">).</li> <BR/></ul>
Legal Information: Ru-MACHO is a registered trademark of Takasago Intl. Corp.
Legal Information: Sold in collaboration with Takasago for research purposes only. Ru-MACHO is a registered trademark of Takasago Intl. Corp. PCT/JP2010-004301.
Packaging: 1, 5 g in glass bottle
Packaging: 250 mg in glass bottle
mp 260-290 °C
UNSPSC 12161600

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