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Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

ALDRICH/746339 - 97%

Synonym: Ru-SNS catalyst

CAS Number: 1462397-86-9
Empirical Formula (Hill Notation): C26H34Cl2NPRuS2
Molecular Weight: 627.63
MDL Number: MFCD26960799
Linear Formula: C26H34Cl2NPRuS2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-746339-100MG 100 mg
 $0.00
1/EA
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45-746339-500MG 500 mg
 $395.00
1/EA		 Add To Favorites
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay 97%
form solid
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
InChI key ZQGMNGJIEYHKBR-UHFFFAOYSA-L
mp 300-310 °C
Quality Level 100 
reaction suitability core: ruthenium
  reagent type: catalyst
SMILES string CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
sustainability Greener Alternative Product
Application: Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters 
Application: Catalyst for the hydrogenation of esters to alcohols.
General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here  for more information.
Legal Information: This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.
Other Notes: "The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."
Packaging: 100, 500 mg in glass bottle
Purity 97%
mp 300-310 °C
UNSPSC 12161600

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