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[Ir(dtbbpy)(ppy)2]PF6

ALDRICH/747769

Synonym: [Ir(dtbbpy)(ppy)2][PF6]; Ir Photocatalyst; [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate

CAS Number: 676525-77-2
Empirical Formula (Hill Notation): C40H40F6IrN4P
Molecular Weight: 913.95
Linear Formula: C40H40F6IrN4P
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-747769-50MG 50 mg
 $111.00
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45-747769-100MG 100 mg
 $212.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 747769-100MG
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 747769-50MG

 

form powder
InChI 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChI key DZARMRZNOUWGQE-UHFFFAOYSA-N
photocatalyst activation 455 nm
Quality Level 100 
reaction suitability core: iridium
  reaction type: Photocatalysis
  reagent type: catalyst
SMILES string CC(C1=CC=[N]([Ir]2([N]3=CC=C(C=C34)C(C)(C)C)([N]5=CC=CC=C5C6=CC=CC=C62)(C7=CC=CC=C78)[N]9=C8C=CC=C9)C4=C1)(C)C.FP(F)(F)(F)(F)F
storage temp. 2-8°C
Application: [Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
• Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
• Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
• Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
• Aryl-alkyl C−C reductive cross-coupling reactions.
Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 )
Packaging: 50, 100 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Storage Temp. 2-8°C
UNSPSC 12161600

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