Iodotrimethylsilane solution
ALDRICH/748854 - 1 M in dichloromethane
Synonym: Iodotrimethylsilane solution; TMS iodine; TMS-I; TMSI; Trimethyliodosilane
Empirical Formula (Hill Notation): C3H9ISi
Molecular Weight: 200.09
Linear Formula: C3H9ISi
Product Type: Chemical
concentration | 1 M in dichloromethane |
density | 1.334 g/mL at 25 °C |
form | liquid |
refractive index | n |
storage temp. | 2-8°C |
Application: | Iodotrimethylsilane can be used as: • A reagent in the hydroiodation of ynamides to yield the important building blocks (E)-α-iodoenamides. • A reagent in the synthesis of (1-iodovinyl) arenes by hydroiodation of trimethylsilyl ethynylarenes. |
General description: | Iodotrimethylsilane [(CH3)3SiI] is an important and versatile organosilicon reagent with wide applications in organic synthesis. It is used as a neutral nucleophilic reagent, trimethylsilylating agent, Lewis acid catalyst, reducing agent and dehydrating agent in many organic reactions. |
Packaging: | 100 mL in glass bottle |
Symbol | GHS02,GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H225 - H314 - H336 - H351 |
Precautionary statements | P201 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Codes | F,C |
Risk Statements | 11-14-34-40 |
Safety Statements | 16-26-36/37/39-45 |
RIDADR | UN 3286 8(6.1)(3) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | -23.8 °F |
Flash Point(C) | -31 °C |
Supplemental Hazard Statements | EUH014 |
Density | 1.334 g/mL at 25 °C |
Refractive Index | n |
Storage Temp. | 2-8°C |
UNSPSC | 12352101 |