Bis[2-(4,6-difluorophenyl)pyridinato-C²,N](picolinato)iridium(III)

ALDRICH/751464 - 97%

Synonym: F₂Irpic; FIrpic

CAS Number: 376367-93-0
Empirical Formula (Hill Notation): C₂₈H₁₆F₄IrN₃O₂
Molecular Weight: 694.66
MDL Number: MFCD09038721
Linear Formula: C₂₈H₁₆F₄IrN₃O₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-751464-250MG	250 mg	$222.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	solid
InChI	1S/2C11H6F2N.C6H5NO2.Ir/c212-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;8-6(9)5-3-1-2-4-7-5;/h21-4,6-7H;1-4H,(H,8,9);/q;;;+1/p-1
InChI key	CTOBHCLNNFAQNN-UHFFFAOYSA-M
mp	330-335 °C
OLED device performance	ITO/NPD/mCP/BCPO:FIrpic (8%)/TAZ/LiF/Al • Color: blue • Max. Luminance: 35677 Cd/m² • Max. EQE: 23.5 % • Turn-On Voltage: 2.8 V
	ITO/PEDOT:PSS/BCC-27: FIrpic (10 wt%)/TAZ/Cs₂CO₃:Al • Color: blue • Max. Luminance: 19200 Cd/m² • Max. EQE: 9.7 % • Turn-On Voltage: 3.9 V
	ITO/PEDOT:PSS/NPD/TCTA/m-CBTZ:FIrpic (10 wt%)/DPPS/TAZ/LiF/Al • Color: blue • Max. Luminance: 29500 Cd/m² • Max. EQE: 8.8 % • Turn-On Voltage: 3.5 V
	ITO/PEDOT:PSS/NPD/TCTA/p-CBTZ:FIrpic (10 wt%)/DPPS/TAZ/LiF/Al • Color: blue • Max. Luminance: 15500 Cd/m² • Max. EQE: 8 % • Turn-On Voltage: 3.5 V
orbital energy	HOMO 5.8 eV
	LUMO 2.9 eV
SMILES string	Fc1cc(F)c(-c2ccccn2)c(c1)[Ir](OC(=O)c3ccccn3)c4cc(F)cc(F)c4-c5ccccn5

Application:	FIrpic is a light blue heteroleptic triplet emitter.This material is typically doped into host matrices such as tetra-aryl silanes and short conjugation length carbazole derivatives in OLEDs; showing a good quantum efficiency.
Packaging:	250 mg in glass insert

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
mp	330-335 °C
UNSPSC	12352103

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