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(Tributylphosphoranylidene)acetonitrile solution

ALDRICH/752959 - 1 M in toluene

Synonym: CMBP solution; Tsunoda reagent; Cyanomethylene)tributylphosphorane

Empirical Formula (Hill Notation): C14H28NP
Molecular Weight: 241.35
MDL Number: MFCD01321151
Linear Formula: C14H28NP
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-752959-1ML 1 mL
 $128.00
1/EA		 Add To Favorites
45-752959-5ML 5 mL
 $390.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 752959-1ML
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 752959-5ML

 

concentration 1 M in toluene
density 0.886 g/mL at 25 °C
form liquid
functional group nitrile
  phosphine
InChI 1S/C14H28NP/c1-4-7-11-16(14-10-15,12-8-5-2)13-9-6-3/h14H,4-9,11-13H2,1-3H3
InChI key OZMLUMPWPFZWTP-UHFFFAOYSA-N
Quality Level 100 
refractive index n/D 1.500 (lit.)
  n20/D 1.501
SMILES string CCCCP(CCCC)(CCCC)=CC#N
storage temp. 2-8°C
General description: (Tributylphosphoranylidene)acetonitrile is a stabilized trialkylphosphorane that can act as a substitute to the diethyl azodicarboxylate and triphenylphosphine (DEAD-TPP) system for Mitsunobu reaction between nucleophiles (HA) and alcohols (ROH) to form RA. It is highly useful when the pKa of the nucleophiles are higher than 11.
Packaging: 1, 5 mL in glass bottle
Density 0.886 g/mL at 25 °C
Refractive Index n/D 1.500 (lit.); n20/D 1.501
Storage Temp. 2-8°C
UNSPSC 12352001

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