RuPhos Pd G2

ALDRICH/753246

Synonym: 2nd Generation RuPhos Precatalyst; Chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II); RuPhos-Pd-G2

CAS Number: 1375325-68-0
Empirical Formula (Hill Notation): C₄₂H₅₃ClNO₂PPd
Molecular Weight: 776.72
MDL Number: MFCD20264899
Linear Formula: C₄₂H₅₃ClNO₂PPd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-753246-250MG	250 mg	$57.90 1/EA	Add To Favorites
45-753246-1G	1 g	$171.00 1/EA	Add To Favorites
45-753246-5G	5 g	$560.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 753246-1G

Properties
Descriptions
Safety Info.
Basic Data

feature	generation 2
form	solid
functional group	phosphine
InChI	1S/C30H43O2P.C12H10N.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key	VPDRBFBKNSFRSS-UHFFFAOYSA-M
mp	195-197 °C
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	Nc1ccccc1-c2ccccc2[Pd]Cl.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6

Application:	RuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction.
General description:	RuPhos Pd G2 is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.
Other Notes:	May contain <1% acetone.
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	195-197 °C
UNSPSC	12161600

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