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Magnesium bis(trifluoromethanesulfonimide)

ALDRICH/753424

Synonym: Magnesium bis(ditriflimide)

CAS Number: 133395-16-1
Empirical Formula (Hill Notation): C4F12MgN2O8S4
Molecular Weight: 584.60
MDL Number: MFCD14156020
Linear Formula: C4F12MgN2O8S4
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-753424-1G 1 g
 $142.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 753424-1G

 

form powder
InChI 1S/2C2F6NO4S2.Mg/c2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q2*-1;+2
InChI key DMFBPGIDUUNBRU-UHFFFAOYSA-N
mp >200 °C
SMILES string FC(F)(F)S(=O)(=O)N([Mg]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F
Application: • Rechargeable Battery Research: Utilized in the study of rechargeable Mg-ion batteries, Magnesium bis(trifluoromethanesulfonimide) serves as a model anode material, providing significant insights into atomistic and mesoscale mechanisms that could revolutionize battery development and application (Kravchyk et al., 2018 ).
General description: Magnesium bis(trifluoromethanesulfonimide) (Mg(TFSI)2) is a strong magnesium Lewis acid. It is used as a catalyst in organic synthesis. For instance, it is used in the synthesis of dihydropyrazoles by reaction of nitrilimines with alkenes. Additionally, Mg(TFSI)2 salt is also useful for ionic conductivity studies, transference number measurements, and electrochemical properties of gel polymer electrolyte (GPE) systems.
General description: Magnesium bis(trifluoromethanesulfonimide), also known as magnesium triflimide, can be used as an inorganic catalyst in various organic reactions, including acetylation of phenols and alcohols, aminolysis of lactones with amines, [2 + 2] cycloadditions of siloxy-alkynes with carbonyl compounds, cycloisomerization of 1,6-dienes, Friedel-Crafts acylation, and for the synthesis of coumarins.
Packaging: 1 g in glass bottle
mp >200 °C
UNSPSC 12352300

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