PCy3 Pd G2

ALDRICH/756741 - 95%

Synonym: Chloro[(tricyclohexylphosphine)-2-(2′-aminobiphenyl)]palladium(II); Tricyclohexylphosphine Pd G2

CAS Number: 1353658-81-7
Empirical Formula (Hill Notation): C₃₀H₄₃ClNPPd
Molecular Weight: 590.52
MDL Number: MFCD21363051
Linear Formula: C₃₀H₄₃ClNPPd
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-756741-1G	1 g	$115.00 1/EA	Add To Favorites
45-756741-5G	5 g	$482.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
feature	generation 2
form	solid
functional group	phosphine
InChI	1S/C18H33P.C12H10N.ClH.Pd/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h16-18H,1-15H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key	CYJRABDADOSMKA-UHFFFAOYSA-M
mp	244-246 °C
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: C-H Activation
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	NC1=C(C2=C([Pd]Cl)C=CC=C2)C=CC=C1.C3(CCCCC3)P(C4CCCCC4)C5CCCCC5

Application:

PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:
• To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
• To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
• In the C-H bond functionalization reactions.

Packaging:

1, 5 g in glass bottle

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	95%
mp	244-246 °C
UNSPSC	12161600

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