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PCy3 Pd G2

ALDRICH/756741 - 95%

Synonym: Chloro[(tricyclohexylphosphine)-2-(2′-aminobiphenyl)]palladium(II); Tricyclohexylphosphine Pd G2

CAS Number: 1353658-81-7
Empirical Formula (Hill Notation): C30H43ClNPPd
Molecular Weight: 590.52
MDL Number: MFCD21363051
Linear Formula: C30H43ClNPPd
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-756741-1G 1 g
 $123.00
1/EA		 Add To Favorites
45-756741-5G 5 g
 $513.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes, it may have been created or edited with AI. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 756741-5G

 

assay 95%
feature generation 2
form solid
functional group phosphine
InChI 1S/C18H33P.C12H10N.ClH.Pd/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h16-18H,1-15H2;1-6,8-9H,13H2;1H;/q;;;+1/p-1
InChI key CYJRABDADOSMKA-UHFFFAOYSA-M
mp 244-246 °C
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: C-H Activation
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string NC1=C(C2=C([Pd]Cl)C=CC=C2)C=CC=C1.C3(CCCCC3)P(C4CCCCC4)C5CCCCC5
Application: PCy3 Pd G2 is a monophosphine-coordinated 2-phenylaniline-based palladacycle complex that can be used as a precatalyst:
• To prepare diarylmethanes by Suzuki cross-coupling reaction with heterocyclic-chloromethyl derivatives with aryl/heteroaryl boronic acids.
• To synthesize poly(arylene)s by the Suzuki cross-coupling polymerization reaction between aryl dihalides and aryldiboronic acids.
• In the C-H bond functionalization reactions.
Packaging: 1, 5 g in glass bottle
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 244-246 °C
UNSPSC 12161600

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