Palladium(II) chloride
ALDRICH/76050 - anhydrous, 60% Pd basis
Synonym: Dichloropalladium; Palladium dichloride; Palladous chloride
CAS Number: 7647-10-1
Empirical Formula (Hill Notation): Cl2Pd
Molecular Weight: 177.33
EC Number: 231-596-2
MDL Number: MFCD00003558
Linear Formula: Cl2Pd
Product Type: Chemical
concentration | 60% Pd |
density | 4 g/mL at 25 °C (lit.) |
form | solid |
InChI | 1S/2ClH.Pd/h2*1H;/q;;+2/p |
InChI key | PIBWKRNGBLPSSY-UHFFFAOYSA |
mp | 678-680 °C (lit.) |
reaction suitability | core: palladium |
reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
reaction type: Heck Reaction | |
reaction type: Hiyama Coupling | |
reaction type: Negishi Coupling | |
reaction type: Sonogashira Coupling | |
reaction type: Stille Coupling | |
reaction type: Suzuki-Miyaura Coupling | |
reagent type: catalyst | |
SMILES string | Cl[Pd]Cl |
Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. |
Application: | Palladium(II) chloride can be used to catalyze: • Cross-coupling reactions between terminal alkynes and aryl iodides or bromides under modified Sonogashira-Cassar-Heck conditions. • Carbonylation of organic tellurides with carbon monoxide to form corresponding methyl carboxylates. • Isomerization of allylic ester in acetic acid. • Carbonylation of amines to form isocyanates. |
Other Notes: | Review |
Packaging: | 1, 5, 25 g in glass bottle |
Symbol | GHS05,GHS07,GHS09 |
Signal word | Danger |
Hazard statements | H290 - H302 - H317 - H318 - H410 |
Precautionary statements | P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310 |
Hazard Codes | T |
Risk Statements | 25-43 |
Safety Statements | 36/37-45 |
RIDADR | UN 3288 6.1 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | 678-680 °C (lit.) |
Density | 4 g/mL at 25 °C (lit.) |
UNSPSC | 12161600 |