(R)-(4,4′,6,6′-Tetramethoxybiphenyl-2,2′-diyl)bis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine

ALDRICH/761419 - 97%

Synonym: (R)-DTBM-Garphos^™

CAS Number: 1365531-98-1
Empirical Formula (Hill Notation): C₇₆H₁₀₈O₈P₂
Molecular Weight: 1211.61
MDL Number: MFCD22666441
Linear Formula: C₇₆H₁₀₈O₈P₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-761419-100MG	100 mg	$130.00 1/EA		Add To Favorites
45-761419-500MG	500 mg	$0.00 1/EA CALL FOR PRICE		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
form	solid
functional group	phosphine
InChI	1S/C76H108O8P2/c1-69(2,3)51-37-47(38-52(65(51)81-29)70(4,5)6)85(48-39-53(71(7,8)9)66(82-30)54(40-48)72(10,11)12)61-35-45(77-25)33-59(79-27)63(61)64-60(80-28)34-46(78-26)36-62(64)86(49-41-55(73(13,14)15)67(83-31)56(42-49)74(16,17)18)50-43-57(75(19,20)21)68(84-32)58(44-50)76(22,23)24/h33-44H,1-32H3
InChI key	KACYLFSRRUJDSY-UHFFFAOYSA-N
optical activity	[α]22/D +18.0°, c = 0.5% in chloroform
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: ligand
SMILES string	COc1cc(OC)c(c(c1)P(c2cc(c(OC)c(c2)C(C)(C)C)C(C)(C)C)c3cc(c(OC)c(c3)C(C)(C)C)C(C)(C)C)-c4c(OC)cc(OC)cc4P(c5cc(c(OC)c(c5)C(C)(C)C)C(C)(C)C)c6cc(c(OC)c(c6)C(C)(C)C)C(C)(C)C

Application:	Versatile chiral diphosphine ligand.
Legal Information:	Garphos is a trademark of Kanata Chemical Technologies, Inc.
Legal Information:	Sold under license from Kanata Chemical Technologies Inc. for research purposes only.
Packaging:	100, 500 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	97%
UNSPSC	12352112

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