cataCXium^® A Pd G3

ALDRICH/761435 - 95%

Synonym: Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II); [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate; cataCXium-A-Pd-G3

CAS Number: 1651823-59-4
Empirical Formula (Hill Notation): C₃₇H₅₂NO₃PPdS
Molecular Weight: 728.27
Linear Formula: C₃₇H₅₂NO₃PPdS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-761435-250MG	250 mg	$152.00 1/EA	Add To Favorites
45-761435-1G	1 g	$393.00 1/EA	Add To Favorites
45-761435-5G	5 g	$1600.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 761435-5G

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
feature	generation 3
form	solid
functional group	phosphine
greener alternative category	Re-engineered
greener alternative product characteristics	Waste Prevention Atom Economy Safer Solvents and Auxiliaries Learn more about the Principles of Green Chemistry .
greener alternative product score	old score: 16 new score: 2 Find out more about DOZN™ Scoring
impurities	≤3% acetone
InChI	1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
InChI key	REYVZCOGMIXVNX-DVBMAMJVSA-M
mp	196-241 °C (decomposition)
Quality Level	100
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
sustainability	Greener Alternative Product

Application:	cataCXium^® A Pd G3 is a Buchwald third-generation precatalyst that can be used in:• Direct ortho-arylation of pyridinecarboxylic acids. • Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes. • Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes. • Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes. • Boroperfluoroalkylation of terminal alkynes. • Copper-free Sonogashira coupling reaction of aromatic halides with alkynes to form C-C bond. • Suzuki cross-coupling between organotrifluoroborate and aryl halides. For small scale and high throughput uses, product is also available as ChemBeads (928305 )
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Atom Economy”. Click here to view its DOZN scorecard.
Legal Information:	cataCXium is a registered trademark of Umicore AG & Co. KG
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	95%
mp	196-241 °C (decomposition)
UNSPSC	12352300

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