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CPhos Pd G3

ALDRICH/763004 - 95%

Synonym: CPhos-G3-Palladacycle; CPhos-Pd-G3; [(2-Dicyclohexylphosphino-2′,6′-bis(N,N-dimethylamino) -1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)] palladium(II) methanesulfonate

CAS Number: 1447963-73-6
Empirical Formula (Hill Notation): C41H54N3O3PPdS
Molecular Weight: 806.34
Linear Formula: C41H54N3O3PPdS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-763004-100MG 100 mg
 $0.00
1/EA
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45-763004-250MG 250 mg
 $182.00
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45-763004-500MG 500 mg
 $323.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763004-5G

 

assay 95%
feature generation 3
form solid
functional group phosphine
InChI 1S/C28H41N2P.C12H10N.CH4O3S.Pd/c1-29(2)25-19-13-20-26(30(3)4)28(25)24-18-11-12-21-27(24)31(22-14-7-5-8-15-22)23-16-9-6-10-17-23;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-23H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key SMFSVINURNWOPR-UHFFFAOYSA-M
mp 176-178 °C (decomposition)
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CN(C)c3cccc(N(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6
General description: CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
Packaging: 100, 250, 500 mg in glass bottle
Packaging: 5 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 176-178 °C (decomposition)
UNSPSC 12161600

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