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sSPhos Pd G2

ALDRICH/763314 - 95%

Synonym: Chloro(sodium-2-dicyclohexylphosphino-2′,6′-dimethoxy-1,1′-biphenyl-3′-sulfonate)[2-(2′-amino-1,1′-biphenyl)]palladium(II)

CAS Number: 2375242-78-5
Empirical Formula (Hill Notation): C38H44ClNNaO5PPdS
Molecular Weight: 822.66
MDL Number: MFCD22377809
Linear Formula: C38H44ClNNaO5PPdS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-763314-100MG 100 mg
 $62.00
1/EA		 Add To Favorites
45-763314-500MG 500 mg
 $240.00
1/EA		 Add To Favorites
45-763314-5G 5 g
 No Price  
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763314-100MG
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 763314-500MG

 

assay 95%
feature generation 2
form solid
functional group phosphine
InChI 1S/C26H35O5PS.C12H10N.ClH.Na.Pd/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);1-6,8-9H,13H2;1H;;/q;;;2*+1/p-2
InChI key MWQYWXJKMDRSJN-UHFFFAOYSA-L
mp 193-194 °C (decomposition)
Quality Level 100 
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
reaction type: Cross Couplings
SMILES string [Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O
Application: sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:
• DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates.
• DNA-compatible hydroxycarbonylation reactions.
• The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid.
Packaging: 100, 500 mg in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 95%
mp 193-194 °C (decomposition)
UNSPSC 12161600

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