RuPhos Pd G3

ALDRICH/763403 - 98%

Synonym: (2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate; RuPhos-G3-Palladacycle; RuPhos-Pd-G3

CAS Number: 1445085-77-7
Empirical Formula (Hill Notation): C₄₃H₅₆NO₅PPdS
Molecular Weight: 836.37
MDL Number: MFCD22572684
Linear Formula: C₄₃H₅₆NO₅PPdS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-763403-250MG	250 mg	$91.10 1/EA	Add To Favorites
45-763403-1G	1 g	$256.00 1/EA	Add To Favorites
45-763403-5G	5 g	$1030.00 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

assay	98%
feature	generation 3
form	solid
functional group	phosphine
InChI	1S/C30H43O2P.C12H10N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key	AXZLIMCJMPNFFU-UHFFFAOYSA-M
mp	188-196 °C (decomposition)
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC(C)Oc3cccc(OC(C)C)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6

Application:	RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:• Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles. • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers. • Suzuki-Miyaura-cross-coupling of aminothiophenes. For small scale and high throughput uses, product is also available as ChemBeads (928283 )
General description:	RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335 - H412
Precautionary statements	P273 - P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38-52/53
Safety Statements	26-61
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	188-196 °C (decomposition)
UNSPSC	12161600

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