Azobisisobutyronitrile
ALDRICH/768375 - 12 wt. % in acetone
Synonym: 2,2′-Azobis(2-methylpropionitrile) solution; radical initiator; α,α,′-Azoisobutyronitrile solution; AIBN solution
CAS Number: 78-67-1
Empirical Formula (Hill Notation): C8H12N4
Molecular Weight: 164.21
MDL Number: MFCD00013808
Linear Formula: C8H12N4
Product Type: Chemical
| concentration | 12 wt. % in acetone |
| density | 0.808 g/mL at 25 °C |
| form | liquid |
| InChI | 1S/C8H12N4/c1-7(2,5-9)11- |
| InChI key | OZAIFHULBGXAKX-VAWYXSNFSA |
| Quality Level | 100 ![]() |
| refractive index | n |
| SMILES string | CC(C)(N=NC(C)(C)C#N)C#N |
| storage temp. | 2-8°C |
| Application: | • Used as an initiator in the synthesis of highly cross-linked Poly(divinylbenzene) (PDVB) polymers. • Used as an initiator in the polymerization process of 2-hydroxyethyl methacrylate (HEMA). |
| Features and Benefits: | Decomposes unimolecularly at good rates without much variation from one solvent to another. |
| General description: | Azobisisobutyronitrile (AIBN) is an azo-compound and is widely used as a free radical initiator. This compound has labile carbon-nitrogen covalent bond which undergoes homolytic scission under thermal, chemical or photochemical conditions producing free radicals. They are useful in many reactions like halogenation, polymerisation of vinyl monomers, grafting reactions, curing of rubbers and unsaturated polymers and cross-linking of polyolefins. |
| Packaging: | 100, 500 mL in glass bottle |
| Symbol | ![]() GHS02,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H319 - H336 |
| Precautionary statements | P210 - P305 + P351 + P338 |
| Hazard Codes | E,Xi |
| Risk Statements | 2-11-36-66-67 |
| Safety Statements | 16-26-35 |
| RIDADR | UN1090 - class 3 - PG 2 - Acetone, solution |
| WGK Germany | WGK 2 |
| Flash Point(F) | 1.4 °F |
| Flash Point(C) | -17 °C |
| Supplemental Hazard Statements | EUH044 - EUH066 |
| Density | 0.808 g/mL at 25 °C |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12162002 |



