[1,3-Bis(diphenylphosphino)propane]palladium(II) triflate

ALDRICH/771384

Synonym: Pd(OTf)₂(dippp)

CAS Number: 137846-38-9
Empirical Formula (Hill Notation): C₂₉H₂₆F₆O₆P₂PdS₂
Molecular Weight: 817.00
MDL Number: MFCD29036994
Linear Formula: C₂₉H₂₆F₆O₆P₂PdS₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-771384-1G	1 g	$385.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solid
InChI	1S/C27H26P2.2CHF3O3S.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;22-1(3,4)8(5,6)7;/h1-12,14-21H,13,22-23H2;2(H,5,6,7);/q;;;+2/p-2
InChI key	MIGUMLGJSGTNOK-UHFFFAOYSA-L
mp	169-183 °C
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst
SMILES string	[Pd++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

Application:	[1,3-Bis(diphenylphosphino)propane]palladium(II) triflate can be used as a catalyst to synthesize phenanthridines by the reaction between 2-halogeno-N-Ms arylamines and benzyl halides/sulfonates via nucleophilic substitution followed by C-H functionalization and aromatization reaction.
Packaging:	1 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332 - H315 - H319
Precautionary statements	P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	169-183 °C
UNSPSC	12161600

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