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N-(2-Hydroxyethyl)maleimide

ALDRICH/773263 - 97%

Synonym: 1-(2-Hydroxyethyl)-pyrrole-2,5-dione; 1-(2-Hydroxyethyl)maleimide; N-(Ethanol)maleimide; HEMI

CAS Number: 1585-90-6
Empirical Formula (Hill Notation): C6H7NO3
Molecular Weight: 141.12
MDL Number: MFCD00465266
Linear Formula: C6H7NO3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-773263-250MG 250 mg
$138.00
1/EA
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45-773263-1G 1 g
$526.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 773263-1G

 

assay 97%
form solid
functional group hydroxyl
  maleimide
InChI 1S/C6H7NO3/c8-4-3-7-5(9)1-2-6(7)10/h1-2,8H,3-4H2
InChI key AXTADRUCVAUCRS-UHFFFAOYSA-N
mp 66-67 °C (lit.)
  67-74 °C
reaction suitability reagent type: cross-linking reagent
SMILES string O=C(N1CCO)C=CC1=O
storage temp. 2-8°C
Application: N-(2-Hydroxyethyl)maleimide can be used:
• In the synthesis of (EFA)-based multifunctional oligoester resins with maleimides as end groups by reacting with 9,10-epoxy-18-hydroxyoctadecanoic acid (EFA) and dimethyl adipate catalyzed by Candida antarctica lipase B (CalB).
• As an initiator in ring-opening polymerization of δ-valerolactone catalyzed by trifluoromethanesulfonimide.
• In one-pot synthesis of bio-based polyurethane-imides by reacting with castor oil, eleostearic acid diethanol amide and isophorone diisocyanate.

Application: N-(2-Hydroxyethyl)maleimide may be used to synthesize [2,2-bis(maleimidoethoxy)-
propane (BMEP)], a protein cross-linking reagent with potential application in constructing immunotoxins. It may also be used in preparing thermoresponsive self-healing polyurethanes with the shape-memory property.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
Symbol GHS07  GHS07
Signal word Warning
Hazard statements H319
Precautionary statements P305 + P351 + P338
Hazard Codes Xn
Risk Statements 22-36
Safety Statements 26
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
mp 66-67 °C (lit.); 67-74 °C
Storage Temp. 2-8°C
UNSPSC 12352111

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