RockPhos Pd G3

ALDRICH/773905

Synonym: RockPhos-G3-palladacycle; [(2-Di-tert-butylphosphino-3-methoxy-6-methyl-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2-aminobiphenyl)]palladium(II) methanesulfonate

CAS Number: 2009020-38-4
Empirical Formula (Hill Notation): C₄₄H₆₂NO₄PPdS
Molecular Weight: 838.43
MDL Number: MFCD27952542
Linear Formula: C₄₄H₆₂NO₄PPdS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-773905-100MG	100 mg	$121.00 1/EAAdd To Favorites	Add To Favorites
45-773905-500MG	500 mg	$571.00 1/EAAdd To Favorites	Add To Favorites
45-773905-5G	5 g	$4240.00 1/EAAdd To Favorites	Add To Favorites

feature	generation 3
form	solid
functional group	phosphine
InChI	1S/C31H49OP.C12H10N.CH4O3S.Pd/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key	PANIJJUVUGSZSP-UHFFFAOYSA-M
mp	220-250 °C
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	CC1=CC=C(OC)C(P(C(C)(C)C)C(C)(C)C)=C1C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C.NC3=CC=CC=C3C4=CC=CC=C4[Pd]OS(C)(=O)=O

Application:	Buchwald 3rd Generation Pd Precatalyst containing bulk RockPhos ligand. This system has been shown to be effective for cross-coupling reactions like the arylation of aliphatic alcohols. Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands
Packaging:	100, 500 mg in glass bottle
Packaging:	5 g in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	220-250 °C
UNSPSC	12161600