Synonym: Grubbs Catalyst® M2; Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)
CAS Number: 536724-67-1
Empirical Formula (Hill Notation): C54H69Cl2N2PRu
Molecular Weight: 949.09
MDL Number: MFCD08667892
Linear Formula: C54H69Cl2N2PRu
Product Type: Chemical
form |
powder |
InChI |
1S/C21H26N2.C18H33P.C15H10.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2 |
InChI key |
MCNUJWCJGIGFBS-UHFFFAOYSA-L |
mp |
159 (d)-162 °C |
Quality Level |
100  |
reaction suitability |
core: ruthenium |
|
reagent type: catalyst |
storage temp. |
2-8°C |
Application: |
• Oxa-Cages Synthesis: Grubbs Catalyst® M202 is utilized in a synthetic approach for creating diverse oxa-cages via olefin metathesis, enhancing the scope of organic synthesis with high selectivity and efficiency in forming complex cyclic structures (Kotha et al., 2024  ). • Phosphoproline Analogues: This article details the stereocontrolled synthesis of complex bicyclic systems, a type of chemical transformation where Grubbs Catalyst® M202 could potentially be applied for enhancing reaction pathways and outcomes in pharmaceutical synthesis (Hernández-Benítez et al., 2024  ).
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Legal Information: |
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG |
Legal Information: |
Product of Umicore
Product License This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer’s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com   |
Packaging: |
100, 500 mg in glass bottle |
Hazard Codes |
Xn |
Risk Statements |
20/21/22-36/38 |
Safety Statements |
26 |
RIDADR |
NONH for all modes of transport |
WGK Germany |
WGK 3 |
Flash Point(F) |
Not applicable |
Flash Point(C) |
Not applicable |
mp |
159 (d)-162 °C |
Storage Temp. |
2-8°C |
UNSPSC |
12161600 |