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Isopropylmagnesium bromide solution

ALDRICH/775797 - 0.75 M in THF

Synonym: 1-Methylethylmagnesium bromide; 2-Propylmagnesium bromide; iso-Propylmagnesium bromide; Bromoisopropylmagnesium

CAS Number: 920-39-8
Empirical Formula (Hill Notation): C3H7BrMg
Molecular Weight: 147.30
MDL Number: MFCD00672110
Linear Formula: (CH3)2MgBr
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-775797-4X25ML 25 mL
 $97.90
4/EA		 Add To Favorites
45-775797-100ML 100 mL
 $103.00
1/EA		 Add To Favorites
45-775797-800ML 800 mL
 $540.00
1/EA		 Add To Favorites

 

concentration 0.75 M in THF
density 0.982 g/mL at 25 °C
form solution
InChI 1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChI key UCJIVFREPMUZDC-UHFFFAOYSA-M
Quality Level 100 
reaction suitability reaction type: Grignard Reaction
SMILES string CC(C)[Mg]Br
storage temp. 2-8°C
Application:
  • Preparation of isopropylmagnesium bromide solutions: In this study, various concentrations of isopropylmagnesium bromide solutions were prepared, detailing their stability and reactivity for use in palladium-catalyzed cross-coupling reactions and other synthetic applications (Vulović et al., 2017 ).
  • Reductive coupling of amides: This research discusses the reductive functionalization of tertiary amides using isopropylmagnesium bromide, providing a novel method for amine synthesis, which is crucial for pharmaceutical chemistry (Xie and Dixon, 2017 ).
  • Synthesis of 1, 2, 3-triazoles: The study explores the use of isopropylmagnesium bromide in the synthesis of 1, 2, 3-triazoles through Grignard reactions, highlighting its role in protecting azides during the reaction process (Namioka et al., 2023 ).
  • Disposable cartridge concept for Grignard reagents: This paper introduces a novel disposable cartridge for the on-demand synthesis of Grignard reagents, including isopropylmagnesium bromide, enhancing the safety and scalability of Grignard reactions (Berton et al., 2020 ).
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 4×25, 100, 800 mL in Sure/Seal™
Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Density 0.982 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352103

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