(η⁵-Cyclopentadienyl)[N,N-dimethyl-Ν′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate

ALDRICH/794139

Synonym: Herzon Reductive Hydration Catalyst

CAS Number: 1603164-23-3
Empirical Formula (Hill Notation): C₁₆H₂₂F₆N₃PRu
Molecular Weight: 502.40
Linear Formula: C₁₆H₂₂F₆N₃PRu
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-794139-100MG	100 mg	$146.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	powder
InChI	1S/C11H17N3.C5H5.F6P.Ru/c1-14(2)9-5-7-12-10-11-6-3-4-8-13-11;1-2-4-5-3-1;1-7(2,3,4,5)6;/h3-4,6,8,10H,5,7,9H2,1-2H3;1-5H;;/q;;-1;+1/b12-10+;;;
InChI key	KUSUXOOKLDLSSI-AKMNYRKMSA-N
mp	>180 °C
reaction suitability	core: ruthenium
	reagent type: catalyst
SMILES string	CN(C)CCC/N=C/C1=NC=CC=C1.F[P-](F)(F)(F)(F)F.[C]2[C][C][C][C]2.[Ru+]

Application:	Catalyst mediates the transformation of alkynes to alcohols through an anti-Markovnikov addition. This reaction occurs at room temperature with the use of formic acid to assist in the reduction of the intermediate aldehyde to the corresponding alcohol.
General description:	(η⁵ -Cyclopentadienyl)[N,N-dimethyl-N′-(2-pyridinylmethylidene)propane-1,3-diamine]ruthenium hexafluorophosphate is also referred to as Herzon reductive hydration catalyst. Herzon reductive hydration catalyst is a half-sandwich ruthenium complex. It is a tridentate nitrogen-based ligand containing a hemilabile 3-(dimethylamino)propyl group. It participates in the conversion of terminal alkynes to linear alcohols.
Other Notes:	A Highly Active and Air-Stable Ruthenium Complex for the Ambient Temperature Anti-Markovnikov Reductive Hydration of Terminal Alkynes
Packaging:	100 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	>180 °C
UNSPSC	12161600

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