Phosphazene base P2-Et
ALDRICH/79417 - ≥98.0% (NT)
Synonym: 1-
CAS Number: 165535-45-5
Empirical Formula (Hill Notation): C12H35N7P2
Molecular Weight: 339.40
MDL Number: MFCD00145113
Linear Formula: [(CH3)2N]3P=NP(=NC2H5)[N(CH3)2]2
Product Type: Chemical
assay | ≥98.0% (NT) |
bp | 96 °C/0.05 mmHg (lit.) |
density | 1.02 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C12H35N7P2/c1-12-13-20 |
InChI key | CFUKEHPEQCSIOM-UHFFFAOYSA |
refractive index | n |
n |
|
SMILES string | CCN=P(N=P(N(C)C)(N(C)C)N( |
Application: | Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases |
Application: | Phosphazene base P2-Et is an extremely strong, neutral nitrogen base. It gives excellent results where other bases fail This strong non-ionic base has the ability to catalyze a wide variety of organic transformations such as: • Palladium-catalyzed cross-coupling reactions when used in combination with tBuXPhos or tBuBrettPhos G3 precatalysts. • Deprotonation of ortho-halobenzyl sulfones to generate α-sulfonyl benzylic carbanions. • Conversion of vinyl sufone to allyl sulfone. • α-Alkylation of 2-phenyl-2-oxazoline-4-ca |
Packaging: | 1, 5 mL in glass bottle |
Symbol | GHS05 |
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3267 8 / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥98.0% (NT) |
bp | 96 °C/0.05 mmHg (lit.) |
Density | 1.02 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352000 |