Stahl Aerobic Oxidation TEMPO solution

ALDRICH/796549 - 0.2 M in acetonitrile, Solution for Oxidation of Primary Alcohols

Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-796549-25ML	25 mL	$137.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	0.2 M in acetonitrile
form	liquid
InChI	1S/C10H8N2.C9H18NO.C4H6N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-8(2)6-5-7-9(3,4)10(8)11;1-6-3-2-5-4-6/h1-8H;5-7H2,1-4H3;2-4H,1H3
InChI key	BQFURWVGIDXRNB-UHFFFAOYSA-N
reaction suitability	reagent type: oxidant
SMILES string	CN1C=CN=C1.CC2(C)CCCC(C)(C)N2[O].C3(C4=NC=CC=C4)=NC=CC=C3
storage temp.	2-8°C

Application:	This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038 ) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group .
General description:	Stahl Aerobic Oxidation TEMPO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and TEMPO. It is widely employed for the oxidation of alcohols.
Other Notes:	Technology Spotlight: Aerobic Alcohol Oxidation Solutions Stable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl- Catalyzed Aerobic Alcohol Oxidation Practical Aerobic Alcohol Oxidation with Cu/Nitroxyl and Nitroxyl/NO_x Catalyst Systems
Packaging:	25 mL in glass bottle

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H225 - H302 + H312 + H332 - H314
Precautionary statements	P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes	F,Xn
Risk Statements	11-20/21/22-36/38
Safety Statements	16-26-36/37
RIDADR	UN 1648 3 / PGII
WGK Germany	WGK 3
Flash Point(F)	35.6 °F
Flash Point(C)	2.0 °C

Storage Temp.	2-8°C
UNSPSC	12352000

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